Both tools help you sharpen a piece of writing before publishing, but they measure different qualities. Keyword Density checks the ratio of your target term to the total word count — a signal to search engines about topic focus. Readability scores how easy the copy is for a human to read (Flesch, grade level).
High keyword density with poor readability reads spammy. Low density with high readability reads pleasant but doesn't rank. Great pages score well on both.